{"id":532,"date":"2022-01-01T10:43:44","date_gmt":"2022-01-01T15:43:44","guid":{"rendered":"https:\/\/caslabs.case.edu\/protasiewicz\/?page_id=532"},"modified":"2026-02-27T11:37:00","modified_gmt":"2026-02-27T16:37:00","slug":"publications","status":"publish","type":"page","link":"https:\/\/caslabs.case.edu\/protasiewicz\/publications\/","title":{"rendered":"Publications"},"content":{"rendered":"

Ekstrom, Zakary T.; Stone, \u00a0Alexander M.; \u00a0Li, Guobi; Hassoun, Hannah D.; \u00a0<\/sup>Kornokovich, Anthony D.; Delgado Rosario, Emalyn; \u00a0<\/sup>Espinosa Ferao, Arturo; \u00a0<\/sup>Zeller, Matthias; Rheingold, Arnold L.; \u00a0<\/sup>Protasiewicz, John D. \u00a0“When Acids and Quinones Replace Metals: Expanding the Toolbox for the Mild Dehydrocoupling of Phosphines<\/em>“, 2026<\/strong>, Inorg. Chem.<\/em> submitted.<\/p>\n

Kornokovich,Anthony D.; Rheingold, Arnold L.; Rikka, Vallabha R.; Tang, Wan Si; Jeevarajan, Judith A.; Protasiewicz, J. D. “Dealkylation as a Strategy to Unconventional Lithium Salts from ortho-Phenyl-phosphonate-boranes<\/em>“, Inorg. Chem.<\/em> 2026<\/strong>, 65<\/em>, 3, 1738\u20131742. https:\/\/doi=10.1021\/acs.inorgchem.5c05101<\/a>.<\/p>\n

Stone, Alexander M.; \u00a0Golden, Andrew R.; \u00a0Daniel, Shan M.; Rheingold, Arnold L.; Protasiewicz, J. D. “Hydrogen Bonding vs Dihydrogen Bonding in the Air Stable Primary Phosphine ortho<\/em>-Phosphinophenol”, Europ. J. Inorg. Chem<\/em>. 2024<\/strong>, 27<\/em>, e202400260 .\u00a0 https:\/\/doi.org\/10.1002\/ejic.202400260<\/a><\/p>\n

Evariste, S.; Harrison, A. M.; Sarkar, S.; Rheingold, A. L.; Dunietz, B. D.; Heinicke, J.;, Delgado Rosaria, E.; Yoon, S.; Teets, T. T.; Protasiewicz, J. D. “Luminescent 1,3-Benzazaphospholes”, RSC Advances<\/em>. 2023<\/strong>, 13, 594-601. https:\/\/doi.org\/10.1039\/D2RA07226B<\/a><\/p>\n

Li, G.; Rheingold, A. L.; Protasiewicz, J. D. “Synthesis and Structural Characterization of Nitro-functionalized Cyclic Hypervalent Iodine Compounds” Polyhedron.<\/em> 2022<\/strong>, 223, <\/em>115988. https:\/\/doi.org\/10.1016\/j.poly.2022.115988<\/a><\/p>\n

Protasiewicz, J. D.; Hering-Jughans, C. “Phosphanylidenephosphoranes” invited chapter in Encyclopedia of Inorganic and Bioinorganic Chemistry<\/em> 2022<\/strong>; John Wiley & Sons Ltd.: p eibc2795. DOI: 10.1002\/9781119951438.eibc2795.<\/p>\n

Ekstrom, Z. T.; Rheingold, A. L.; Protasiewicz, J. D. “Synthesis and Structural Characterization of Two Rotationally Flexible Bis(benzoxaphosphole)s” Phosphorus Sulfur Silicon Relat. Elem. (invited, special issue dedicated to Francois Mathey)<\/em> 2022<\/strong>, 426-433 (https:\/\/doi.org\/10.1080\/10426507.2021.2011887<\/a>)<\/em>.<\/p>\n

Li, G.; Smith, R.; Gembicky, M.; Rheingold, A. L.; Protasiewicz, J. D., \u201cSterically crowded 1,4-diiodobenzene as a precursor to difunctional hypervalent iodine compounds\u201d Chem. Commun. <\/em>2022<\/strong>, in press.\u00a0 https:\/\/doi.org\/10.1039\/d1cc06486j<\/a><\/p>\n

Sarkaran, S.; Durairaj, P.; Protasiewicz, J. D.; Dunietz, B. D., \u201cEnhancing fluorescence and lowering the optical gap through C=P doping of a -conjugated molecular backbone: A computational-based design approach\u201d J. Photochem. Photobiology (invited, special issue for SERMCAS conference) <\/em>2021,<\/strong> 8<\/em>, 1000892-1000898.\u00a0 https:\/\/doi.org\/10.1016\/j.jpap.2021.100089<\/a><\/p>\n

Li, G.; Rheingold, A. L.; Protasiewicz, J. D., \u201cSolid State Aggregation of Cyclic Iodonium Ylides\u201d Arkivoc (invited, special issue on Hypervalent Iodine – ICHIC Moscow Conference) <\/em>2021<\/strong>.\u00a0https:\/\/doi.org\/10.24820\/ark.5550190.p011.667<\/a><\/p>\n

Li, G.; Rheingold, A. L.; Protasiewicz, J. D., \u201cRemote Substituents as Potential Control Elements for the Solid-State Structures of Hypervalent Iodine(III) Compounds\u201d Inorg. Chem. <\/em>2021,<\/strong> 60<\/em> (11), 7865-7875.\u00a0 https:\/\/doi.org\/10.1021\/acs.inorgchem.1c00339<\/a><\/p>\n

Grimm, A. B.; Wang, K.; Rheingold, A. L.; Moore, C. E.; Szieberth, D.; Nyulaszi, L.; Protasiewicz, J. D., \u201c2-Aryl-1,3-Benzoxaphospholes as Unwilling Participants for Catalytic Suzuki-Miyaura CC Coupling Reactions\u201d Organometallics <\/em>2021,<\/strong> 40<\/em> (20), 3436-3444.\u00a0 https:\/\/doi.org\/10.1021\/acs.organomet.1c00462<\/a><\/p>\n

Ekstrom, Z. T.; Rheingold, A. L.; Protasiewicz, J. D., \u201cSynthesis and structural characterization of two rotationally flexible bis(benzoxaphosphole)s\u201d Phosphorus, Sulfur Silicon Relat. Elem. Iinvited, special issue dedicated to Francois Mathey) <\/em>2021<\/strong>, in press.\u00a0 https:\/\/doi.org\/10.1080\/10426507.2021.2011887<\/a><\/p>\n

Delgado Rosario, E.; Rectenwald, M. F.; Gaffen, J. R.; Rheingold, A. L.; Protasiewicz, J. D., \u201cOrganophosphorus decorated lithium borate and phosphate salts with extended \u03c0-conjugated backbone\u201d Dalton Trans. <\/em>2021,<\/strong> 50<\/em> (19), 6667-6672.\u00a0 https:\/\/doi.org\/10.1039\/D1DT00601K<\/a><\/p>\n

Kinney, Z. J.; Rheingold, A. L.; Protasiewicz, J. D., \u201cPreferential N-H\u00b7\u00b7\u00b7:C hydrogen bonding involving ditopic NH-containing systems and N-heterocyclic carbenes\u201d RSC Adv. <\/em>2020,<\/strong> 10<\/em> (69), 42164-42171.\u00a0 https:\/\/doi.org\/10.1039\/D0RA08490E<\/a><\/p>\n

Kieser, J. M.; Kinney, Z. J.; Gaffen, J. R.; Evariste, S.; Harrison, A. M.; Rheingold, A. L.; Protasiewicz, J. D., \u201cThree Ways Isolable Carbenes Can Modulate Emission of NH-Containing Fluorophores\u201d J. Am. Chem. Soc. <\/em>2019,<\/strong> 141<\/em> (30), 12055-12063.\u00a0 https:\/\/doi.org\/10.1021\/jacs.9b04864<\/a><\/p>\n

Sarkar, S.; Protasiewicz, J. D.; Dunietz, B. D., \u201cControlling the Emissive Activity in Heterocyclic Systems Bearing C=P Bonds\u201d J. Phys. Chem. Lett. <\/em>2018,<\/strong> 9<\/em> (13), 3567-3572.\u00a0 https:\/\/doi.org\/10.1021\/acs.jpclett.8b01045<\/a><\/p>\n

Gilliard, R. J.; Kieser, J. M.; Protasiewicz, J. D., Synthons for the Development of New Organophosphorus Functional Materials. In Main Group Strategies towards Functional Hybrid Materials<\/em>, Baumgartner, T.; J\u00e4kle, F., Eds. John Wiley & Sons, Inc.: 2018; pp 357-393.\u00a0 https:\/\/doi.org\/10.1002\/9781119235941.ch14<\/a><\/p>\n

Gilliard, R. J.; Heift, D.; Benko, Z.; Keiser, J. M.; Rheingold, A. L.; Grutzmacher, H.; Protasiewicz, J. D., \u201cAn isolable magnesium diphosphaethynolate complex\u201d Dalton Trans. <\/em>2018,<\/strong> 47<\/em> (3), 666-669.\u00a0 https:\/\/doi.org\/10.1039\/C7DT04539E<\/a><\/p>\n

Kieser, J. M.; Gilliard, J. R. J.; Rheingold, A. L.; Grutzmacher, H.; Protasiewicz, J. D., \u201cInsertion of sodium phosphaethynolate, Na[OCP], into a zirconium-benzyne complex\u201d Chem. Commun. <\/em>2017,<\/strong> 53<\/em> (37), 5110-5112.\u00a0 https:\/\/doi.org\/10.1039\/C7CC01482A<\/a><\/p>\n

Grimm, A. B.; Evariste, S.; Rheingold, A. L.; Moore, C. E.; Protasiewicz, J. D., \u201cTungsten pentacarbonyl complexes of 1,3-benzoxaphospholes\u201d J. Organomet. Chem. <\/em>2017,<\/strong> 851<\/em>, 9-13.\u00a0 https:\/\/doi.org\/10.1016\/j.jorganchem.2017.08.021<\/a><\/p>\n

Gilliard, R. J.; Suter, R.; Schrader, E.; Benko, Z.; Rheingold, A. L.; Grutzmacher, H.; Protasiewicz, J. D., \u201cSynthesis of P2C2O2 and P2CO via NHC-mediated coupling of the phosphaethynolate anion\u201d Chem. Commun. <\/em>2017,<\/strong> 53<\/em> (91), 12325-12328.\u00a0 https:\/\/doi.org\/10.1039\/C7CC07654A<\/a><\/p>\n

Wu, S.; Rheingold, A. L.; Golen, J. A.; Grimm, A. B.; Protasiewicz, J. D., \u201cSynthesis of a Luminescent Azaphosphole\u201d Eur. J. Inorg. Chem. <\/em>2016,<\/strong> 2016<\/em> (5), 768-773.\u00a0 https:\/\/doi.org\/10.1002\/ejic.201501279<\/a><\/p>\n

Protasiewicz, J. D., \u201cOrganoiodine(III) reagents as active participants and ligands in transition metal-catalyzed reactions: iodosylarenes and (imino) iodoarenes\u201d Top. Curr. Chem. <\/em>2016,<\/strong> 373<\/em>, 263-288.\u00a0 https:\/\/doi.org\/10.1007\/128_2015_664<\/a><\/p>\n

Pignotti, L. R.; Luck, R. L.; Deligonul, N.; Protasiewicz, J. D.; Johnson, K. E.; Nguyen, L. P.; Urnezius, E., \u201cBimetallic nickel complexes supported by 2,5-bis(phosphine)-1,4-hydroquinonate ligands. Structural, electrochemical and theoretical investigations\u201d Inorg. Chim. Acta <\/em>2015,<\/strong> 424<\/em>, 274-285.\u00a0 https:\/\/doi.org\/10.1016\/j.ica.2014.08.049<\/a><\/p>\n

Zhdankin, V. V.; Protasiewicz, J. D., \u201cDevelopment of new hypervalent iodine reagents with improved properties and reactivity by redirecting secondary bonds at iodine center\u201d Coordination Chemistry Reviews <\/em>2014,<\/strong> 275<\/em>, 54-62.\u00a0 https:\/\/doi.org\/10.1016\/j.ccr.2014.04.007<\/a><\/p>\n

Rectenwald, M. F.; Gaffen, J. R.; Rheingold, A. L.; Morgan, A. B.; Protasiewicz, J. D., \u201cPhosphoryl-Rich Flame-Retardant Ions (FRIONs): Towards Safer Lithium-Ion Batteries\u201d Angewandte Chemie, International Edition <\/em>2014,<\/strong> 53<\/em>(16), 4173-4176.\u00a0 https:\/\/doi.org\/10.1002\/anie.201310867<\/a><\/p>\n

Wu, S.; Deligonal, N.; Protasiewicz, J. D., \u201cAn unusually unstable ortho-phosphinophenol and its use to prepare benzoxaphospholes having enhanced air-stability\u201d Dalton Trans. <\/em>2013,<\/strong> 42<\/em>, 14866-14874 https:\/\/doi.org\/10.1039\/C3DT51919H<\/a><\/p>\n

Simpson, M. C.; Protasiewicz, J. D., \u201cPhosphorus as a carbon copy and as a photocopy: new conjugated materials featuring multiply bonded phosphorus\u201d Pure and Applied Chemistry <\/em>2013,<\/strong> 85<\/em> (4), 801-815.\u00a0 https:\/\/doi.org\/10.1351\/PAC-CON-12-09-13<\/a><\/p>\n

Protasiewicz, J. D., Chapter 1.12 Multiply bonded compounds of group 15 elements. In Comprehensive Inorganic Chemistry II<\/em>, Reedijk, J.; Poeppelmeier, K., Eds. Elsevier: 2013; Vol. 1, pp 325-348.\u00a0 https:\/\/doi.org\/10.1016\/B978-0-08-097774-4.00114-5<\/a><\/p>\n

Protasiewicz, J. D., \u201cNitrogen, phosphorus, arsenic, antimony, and bismuth\u201d Annu. Rep. Prog. Chem., Sect, A: Inorg. Chem. <\/em>2013,<\/strong> 109<\/em>, 66-79.\u00a0 https:\/\/doi.org\/10.1039\/C3IC90011H<\/a><\/p>\n

Laughlin, F. L.; Deligonal, N.; Rheingold, A. L.; Golen, J. A.; Protasiewicz, J. D., \u201cFluorescent Heteroacenes with Multiply-Bonded Phosphorus\u201d Organometallics <\/em>2013,<\/strong> 32<\/em>, 7116-7121.\u00a0 https:\/\/doi.org\/10.1021\/om400838g<\/a><\/p>\n

Laughlin, B. J.; Duniho, T. L.; Homsi, S. J. E.; Levy, B. E.; Deligonul, N.; Gaffen, J. R.; Protasiewicz, J. D.; Tennyson, A. G.; Smith, R. C., \u201cComparison of 1,4-distyrylfluorene and 1,4-distyrylbenzene analogues: synthesis, structure, electrochemistry and photophysics\u201d Org. Biomol. Chem. <\/em>2013,<\/strong> 11<\/em>, 5425-5434.\u00a0 https:\/\/doi.org\/10.1039\/C3OB40580J<\/a><\/p>\n

Ay, B.; Yildiz, E.; Protasiewicz, J. D.; Rheingold, A. L., \u201cHydrothermal synthesis, crystal structure and heterogeneous catalytic activity of a novel inorganic-organic hybrid complex, possessing infinite La-O-La linkages\u201d Inorg. Chim. Acta <\/em>2013,<\/strong> 399<\/em>, 208-213.\u00a0 https:\/\/dx.doi.org\/10.1016\/j.ica.2013.01.026<\/a><\/p>\n

Protasiewicz, J. D., \u201cCoordination-Like Chemistry of Phosphinidenes by Phosphanes\u201d Eur. J. Inorg. Chem. <\/em>2012,<\/strong> 2012<\/em>(29), 4539-4549.\u00a0 https:\/\/doi.org\/10.1002\/ejic.201200273<\/a><\/p>\n

Peng, H.-L.; Payton, J. L.; Protasiewicz, J. D.; Simpson, M. C., \u201cP:P bond photophysics in an Ar-P:P-Ar diphosphene\u201d Dalton Trans. <\/em>2012,<\/strong> 41<\/em> (42), 13204-13209.\u00a0 https:\/\/doi.org\/10.1039\/C2DT30568B<\/a><\/p>\n

Laughlin, F. L.; Rheingold, A. L.; Deligonul, N.; Laughlin, B. J.; Smith, R. C.; Higham, L. J.; Protasiewicz, J. D., \u201cNaphthoxaphospholes as examples of fluorescent phospha-acenes\u201d Dalton Trans. <\/em>2012,<\/strong> 41<\/em> (39), 12016-12022.\u00a0 https:\/\/doi.org\/10.1039\/C2DT30902E<\/a><\/p>\n

Yang, Y.; Samas, B.; Kennedy, V. O.; Macikenas, D.; Chaloux, B. L.; Miller, J. A.; Speer, R. L.; Protasiewicz, J.; Pinkerton, A. A.; Kenney, M. E., \u201cLong, Directional Interactions in Cofacial Silicon Phthalocyanine Oligomers\u201d J. Phys. Chem. A <\/em>2011,<\/strong> 115<\/em> (45), 12474-12485.\u00a0 https:\/\/doi.org\/10.1021\/jp2019445<\/a><\/p>\n

Washington, M. P.; Payton, J. L.; Simpson, M. C.; Protasiewicz, J. D., \u201cRedox Behavior of 2-Substituted 1,3-Benzoxaphospholes and 2,6-Substituted Benzo[1,2-d:4,5-d\u2019]bisoxaphospholes\u201d Organometallics <\/em>2011,<\/strong> 30<\/em>, 1975-1983.\u00a0 https:\/\/doi.org\/10.1021\/om200014f<\/a><\/p>\n

Duraj, S. A.; Hepp, A. F.; Woloszynek, R.; Protasiewicz, J. D.; Dequeant, M.; Ren, T., \u201cSynthesis of two new group 13 benzoato-chloro complexes: A structural study of gallium and indium chelating carboxylates\u201d Inorg. Chim. Acta <\/em>2011,<\/strong>365<\/em> (1), 54-60.\u00a0 https:\/\/doi.org\/10.1016\/j.ica.2010.08.026<\/a><\/p>\n

Washington, M. P.; Gudimetla, V. B.; Laughlin, F. L.; Deligonul, N.; He, S.; Payton, J. L.; Simpson, M. C.; Protasiewicz, J. D., \u201cPhosphorus can also be a \u201cphotocopy\u201d\u201d J. Am. Chem. Soc. <\/em>2010,<\/strong> 132<\/em> (13), 4566-4567.\u00a0 https:\/\/doi.org\/10.1021\/ja1009426<\/a><\/p>\n

Shaffer, A. R.; Deligonul, N.; Scherson, D. A.; Protasiewicz, J. D., \u201cA Hybrid Lithium Oxalate-Phosphinate Salt\u201d Inorg. Chem. <\/em>2010,<\/strong> 49<\/em> (23), 10756-10758.\u00a0 https:\/\/doi.org\/10.1021\/ic1018532<\/a><\/p>\n

Protasiewicz, J. D.; Washington, M. P.; Gudimetla, V. B.; Payton, J. L.; Simpson, M. C., \u201cA closer look at the phosphorus-phosphorus double bond lengths in meta<\/em>-terphenyl substituted diphosphenes\u201d Inorg. Chem. Acta. (special issue Prof. Arnold Rheingold) <\/em>2010,<\/strong> 364<\/em>, 39-45.\u00a0 https:\/\/doi.org\/10.1016\/j.ica.2010.07.018<\/a><\/p>\n

Meprathu, B.; Protasiewicz, J. D., \u201cEnhancing the solubility for hypervalent ortho<\/em>-sulfonyl iodine compounds\u201d Tetrahedron <\/em>2010,<\/strong> 66<\/em>, 5768-5774.\u00a0 https:\/\/doi.org\/10.1016\/j.tet.2010.04.087<\/a><\/p>\n

Justik, M. W.; Kristufek, S. L.; Protasiewicz, J. D.; Deligonul, N., \u201cStereoselective synthesis and x-ray structures of alkenyliodonium salts with a pyridine N-oxide moiety\u201d Synthesis <\/em>2010,<\/strong>\u00a0 (14), 2345-2347.\u00a0 https:\/\/doi.org\/10.1055\/s-0029-1218791<\/a><\/p>\n

Gudimetla, V. B.; Ma, L.; Washington, M. P.; Payton, J. L.; Cather Simpson, M.; Protasiewicz, J. D., \u201cmeta-Terphenyl phosphaalkenes bearing electron-donating and -accepting groups\u201d Eur. J. Inorg. Chem. <\/em>2010,<\/strong>\u00a0 (6), 854-865.\u00a0https:\/\/doi.org\/10.1002\/ejic.200900870<\/a><\/p>\n

Duraj, S. A.; Hepp, A. F.; Woloszynek, R. A.; Protasiewicz, J. D.; Dequeant, M.; Ren, T., \u201cSynthesis and structural study of two new heteroleptic chloro-benzoato complexes: Structurally-characterized chelated gallium carboxylate and seven-coordinate indium benzoate structures\u201d Inorg. Chim. Acta <\/em>2010,<\/strong> 365<\/em>, 54-60.\u00a0 https:\/\/doi.org\/10.1016\/j.ica.2010.08.026<\/a><\/p>\n

Zhang, L.; Xi, B.; Liu, I. P. C.; Choudhuri, M. M. R.; Crutchley, R. J.; Updegraff, J. B.; Protasiewicz, J. D.; Ren, T., \u201cSpectroscopy and Electronic Structures of Ru2(ap)4-alkynyl Compounds\u201d Inorg. Chem. <\/em>2009,<\/strong> 48<\/em>, 5187-5194.\u00a0 https:\/\/doi.org\/10.1021\/ic9000973<\/a><\/p>\n

Schroder, P. M.; Spilker, T. F.; Luu, W.; Updegraff, J. B., III; Kwan, M. L.; Challen, P. R.; Protasiewicz, J. D., \u201cImproved synthesis of pincer ligand precursor, and synthesis and structural characterization of terphenyl scaffolded S-C-S palladium pincer complex\u201d Inorganic Chemistry Communications <\/em>2009,<\/strong> 12<\/em> (12), 1171-1174.\u00a0 https:\/\/doi.org\/10.1016\/j.inoche.2009.08.036<\/a><\/p>\n

Peng, H.-L.; Payton, J. L.; Protasiewicz, J. D.; Simpson, M. C., \u201cTwisting the Phenyls in Aryl Diphosphenes (Ar-P=P-Ar). Significant Impact upon Lowest Energy Excited States\u201d J. Phys. Chem. A <\/em>2009,<\/strong> 113<\/em> (25), 7054-7063.\u00a0 https:\/\/doi.org\/10.1021\/jp810119k<\/a><\/p>\n

Partyka, D. V.; Washington, M. P.; Updegraff, J. B.; Chen, X.; Incarvito, C. D.; Rheingold, A. L.; Protasiewicz, J. D., \u201cSurveying the {AuCl} adducts of bulky phosphines bearing the 2,6-dimesitylphenyl group\u201d J. Organomet. Chem. <\/em>2009,<\/strong> 694<\/em> (9-10), 1441-1446.\u00a0 https:\/\/doi.org\/10.1016\/j.jorganchem.2008.12.051<\/a><\/p>\n

Partyka, D. V.; Washington, M. P.; Gray, T. G.; Updegraff, J. B., III; Turner, J. F., II; Protasiewicz, J. D., \u201cUnusual Phosphorus-Phosphorus Double Bond Contraction upon Mono- and Di-auration of a Diphosphene\u201d J. Am. Chem. Soc. <\/em>2009,<\/strong> 131<\/em> (29), 10041-10048.\u00a0 https:\/\/doi.org\/10.1021\/ja900813v<\/a><\/p>\n

Lipke, M. C.; Woloszynek, R. A.; Ma, L.; Protasiewicz, J. D., \u201cm-Terphenyl Anchored Palladium Diphosphinite PCP-Pincer Complexes That Promote the Suzuki-Miyaura Reaction Under Mild Conditions\u201d Organometallics <\/em>2009,<\/strong> 28<\/em> (1), 188-196.\u00a0 https:\/\/doi.org\/10.1021\/om800626b<\/a><\/p>\n

Kilgore, U. J.; Fan, H.; Pink, M.; Urnezius, E.; Protasiewicz, J. D.; Mindiola, D. J., \u201cPhosphinidene group-transfer with a phospha-Wittig reagent: a new entry to transition metal phosphorus multiple bonds\u201d Chem. Commun. (Cambridge, U. K.) <\/em>2009,<\/strong>\u00a0 (30), 4521-4523.\u00a0 https:\/\/doi.org\/10.1039\/B910410K<\/a><\/p>\n

Justik, M. W.; Protasiewicz, J. D.; Updegraff, J. B., \u201cPreparation and X-ray structures of 2-[(aryl)iodonio]benzenesulfonates: novel diaryliodonium betaines\u201d Tetrahedron Letters <\/em>2009,<\/strong> 50<\/em> (44), 6072-6075.\u00a0 https:\/\/doi.org\/10.1016\/j.tetlet.2009.08.067<\/a><\/p>\n

Thirupathi, N.; Amoroso, D.; Bell, A.; Protasiewicz, J. D., \u201cLatent cationic palladium(II) phosphine carboxylate complexes for norbornene polymerization\u201d Journal of Polymer Science, Part A: Polymer Chemistry <\/em>2008,<\/strong> 47<\/em> (1), 103-110.\u00a0 https:\/\/doi.org\/10.1002\/pola.23125<\/a><\/p>\n

Partyka, D. V.; Washington, M. P.; Updegraff, J. B., III; Woloszynek, R. A.; Protasiewicz, J. D., \u201cSynergistic binding of both Lewis acids and bases to phosphinidenes\u201d Angewandte Chemie, International Edition <\/em>2008,<\/strong> 47<\/em> (39), 7489-7492.\u00a0 https:\/\/doi.org\/10.1002\/anie.200801741<\/a><\/p>\n

Kunzelman, J.; Kinami, M.; Crenshaw, B. R.; Protasiewicz, J. D.; Weder, C., \u201cOligo(p-phenylene vinylene)s as a \u201cnew\u201d class of piezochromic fluorophores\u201d Advanced Materials (Weinheim, Germany) <\/em>2008,<\/strong> 20<\/em> (1), 119-122.\u00a0 https:\/\/doi.org\/10.1002\/adma.200701772<\/a><\/p>\n

Zhang, L.; Huang, Z.; Chen, W.-Z.; Negishi, E.-i.; Fanwick, P. E.; Updegraff, J. B.; Protasiewicz, J. D.; Ren, T., \u201cNegishi Coupling – Expedient Formation of Biphenyls on the Periphery of Inorganic\/Organometallic Diruthenium Species\u201d Organometallics <\/em>2007,<\/strong> 26<\/em> (26), 6526-6528.\u00a0 https:\/\/doi.org\/10.1021\/om701083q<\/a><\/p>\n

Thirupathi, N.; Amoroso, D.; Bell, A.; Protasiewicz, J. D., \u201cReactivity Studies of Cationic Palladium(II) Phosphine Carboxylate Complexes with Lewis Bases: Substitution versus Cyclometalation\u201d Organometallics <\/em>2007,<\/strong> 26<\/em> (13), 3157-3166.\u00a0 https:\/\/doi.org\/10.1021\/om070069g<\/a><\/p>\n

Pearson, A. J.; Protasiewicz, J. D.; Updegraff, J.; Zhang, M., \u201cStereoselective conjugate additions of Grignard reagents to cyclopentadienones\u201d Tetrahedron Letters <\/em>2007,<\/strong> 48<\/em> (31), 5569-5572.\u00a0 https:\/\/doi.org\/10.1016\/j.tetlet.2007.05.125<\/a><\/p>\n

Ma, L.; Wobser, S. D.; Protasiewicz, J. D., \u201cA new platform for NCN dimethylamino pincer complexes: Synthesis and structural studies\u201d J. Organomet. Chem. <\/em>2007,<\/strong> 692<\/em> (24), 5331-5338.\u00a0 https:\/\/doi.org\/10.1016\/j.jorganchem.2007.08.004<\/a><\/p>\n

Ma, L.; Imbesi, P. M.; Updegraff, J. B., III; Hunter, A. D.; Protasiewicz, J. D., \u201cSynthesis and Structural Studies of NCN Diimine Palladium Pincer Complexes Bearing m-Terphenyl Scaffolds\u201d Inorg. Chem. <\/em>2007,<\/strong> 46<\/em> (13), 5220-5228.\u00a0 https:\/\/doi.org\/10.1021\/ic062476a<\/a><\/p>\n

Chen, W.-Z.; Protasiewicz, J. D.; Davis, S. A.; Updegraff, J. B.; Ma, L.-Q.; Fanwick, P. E.; Ren, T., \u201cOlefin Metathesis as an Inorganic Synthetic Tool: Cross and Ring Closing Metathesis Reactions of Diruthenium-Bound w-Alkene-alpha -carboxylates\u201d Inorg. Chem. <\/em>2007,<\/strong> 46<\/em> (9), 3775-3782.\u00a0 https:\/\/doi.org\/10.1021\/ic070123l<\/a><\/p>\n

Xu, G.-L.; Xi, B.; Updegraff, J. B.; Protasiewicz, J. D.; Ren, T., \u201c1,6-Bis(ferrocenyl)-1,3,5-hexatriyne: Novel Preparation and Structural Study\u201d Organometallics <\/em>2006,<\/strong> 25<\/em> (22), 5213-5215.\u00a0 https:\/\/doi.org\/10.1021\/om0607550<\/a><\/p>\n

Smith, R. C.; Gleason, L. B.; Protasiewicz, J. D., \u201cSolution and film photoluminescence of mesityl-substituted PPVs and low molecular weight models\u201d Journal of Materials Chemistry <\/em>2006,<\/strong> 16<\/em> (25), 2445-2452.\u00a0 https:\/\/doi.org\/10.1039\/B601824F<\/a><\/p>\n

Ma, L.; Woloszynek, R. A.; Chen, W.; Ren, T.; Protasiewicz, J. D., \u201cA New Twist on Pincer Ligands and Complexes\u201d Organometallics <\/em>2006,<\/strong> 25<\/em> (14), 3301-3304.\u00a0 https:\/\/doi.org\/10.1021\/om060256z<\/a><\/p>\n

Gudimetla, V. B.; Rheingold, A. L.; Payton, J. L.; Peng, H.-L.; Simpson, M. C.; Protasiewicz, J. D., \u201cPhotochemical E-Z Isomerization of meta-Terphenyl-Protected Phosphaalkenes and Structural Characterizations\u201d Inorg. Chem. <\/em>2006,<\/strong> 45<\/em>(13), 4895-4901.\u00a0 https:\/\/doi.org\/10.1021\/ic0520521<\/a><\/p>\n

Chen, W.-Z.; Protasiewicz, J. D.; Shirar, A. J.; Ren, T., \u201cDimerization of diruthenium coordination compounds via olefin metathesis\u201d Eur. J. Inorg. Chem. <\/em>2006,<\/strong>\u00a0 (23), 4737-4740.\u00a0 https:\/\/doi.org\/10.1002\/ejic.200600831<\/a><\/p>\n

Thirupathi, N.; Amoroso, D.; Bell, A.; Protasiewicz, J. D., \u201cSynthesis and Reactivity of Cationic Palladium Phosphine Carboxylate Complexes\u201d Organometallics <\/em>2005,<\/strong> 24<\/em>, 4099-4102.\u00a0 https:\/\/doi.org\/10.1021\/om050356p<\/a><\/p>\n

Smith, R. C.; Bodner, C. R.; Earl, M. J.; Sears, N. C.; Hill, N. E.; Bishop, L. M.; Sizemore, N.; Hehemann, D. T.; Bohn, J. J.; Protasiewicz, J. D., \u201cSuzuki and Heck coupling reactions mediated by palladium complexes bearing trans-spanning diphosphines\u201d J. Organomet. Chem. <\/em>2005,<\/strong> 690<\/em>, 477-481.\u00a0 https:\/\/doi.org\/10.1016\/j.jorganchem.2004.09.077<\/a><\/p>\n

Meprathu, B. V.; Justik, M. W.; Protasiewicz, J. D., \u201cortho<\/em>-Phosphoryl stabilized hypervalent iodosyl- and iodyl-benzene reagents\u201d Tetrahedron Letters <\/em>2005,<\/strong> 46<\/em> (31), 5187-5190.\u00a0 https:\/\/doi.org\/10.1016\/j.tetlet.2005.05.111<\/a><\/p>\n

Ma, L.; Smith, R. C.; Protasiewicz, J. D., \u201cSelf-assembly of cationic palladium complexes by redistribution of pyridine ligands\u201d Inorg. Chim. Acta <\/em>2005,<\/strong> 358<\/em> (12), 3478-3482.\u00a0 https:\/\/doi.org\/10.1016\/j.ica.2005.04.015<\/a><\/p>\n

Hai, B.; Wu, J.; Chen, X.; Protasiewicz John, D.; Scherson Daniel, A., \u201cMetal-ion adsorption on carboxyl-bearing self-assembled monolayers covalently bound to magnetic nanoparticles\u201d Langmuir <\/em>2005,<\/strong> 21<\/em> (7), 3104-5.\u00a0 https:\/\/doi.org\/10.1021\/la0487139<\/a><\/p>\n

Chen, X.; Chen, W.; Ren, T.; Protasiewicz, J. D., \u201cA cyclic diphosphinite by a formal [4+4] cycloaddition reaction of beta -phosphaenone\u201d Tetrahedron Letters <\/em>2005,<\/strong> 46<\/em> (35), 5941-5944.\u00a0 https:\/\/doi.org\/10.1016\/j.tetlet.2005.06.131<\/a><\/p>\n

Smith, R. C.; Woloszynek, R. A.; Chen, W.; Ren, T.; Protasiewicz, J. D., \u201cSuzuki reactions catalyzed by palladium complexes bearing the bulky (2,6-dimesitylphenyl)dimethylphosphine\u201d Tetrahedron Letters <\/em>2004,<\/strong> 45<\/em> (45), 8327-8330.\u00a0 https:\/\/doi.org\/10.1016\/j.tetlet.2004.09.069<\/a><\/p>\n

Smith, R. C.; Protasiewicz, J. D., \u201cA Trans-Spanning Diphosphine Ligand Based on a m-Terphenyl Scaffold and Its Palladium and Nickel Complexes\u201d Organometallics <\/em>2004,<\/strong> 23<\/em> (18), 4215-4222.\u00a0 https:\/\/doi.org\/10.1021\/om049662d<\/a><\/p>\n

Smith, R. C.; Protasiewicz, J. D., \u201cConjugated Polymers Featuring Heavier Main Group Element Multiple Bonds: A Diphosphene-PPV\u201d J. Am. Chem. Soc. <\/em>2004,<\/strong> 126<\/em> (8), 2268-2269.\u00a0 https:\/\/doi.org\/10.1021\/ja0394683<\/a><\/p>\n

Smith, R. C.; Protasiewicz, J. D., \u201cSystematic investigation of PPV analogue oligomers incorporating low-coordinate phosphorus centres\u201d Europ. J. Inorg. Chem. <\/em>2004,<\/strong>\u00a0 (5), 998-1006.\u00a0 https:\/\/doi.org\/10.1002\/ejic.200300551<\/a><\/p>\n

Smith, R. C.; Gantzel, P.; Rheingold, A. L.; Protasiewicz, J. D., \u201cArsa-Wittig Complexes (ArAs:PMe3) as Intermediates to Diarsenes\u201d Organometallics <\/em>2004,<\/strong> 23<\/em> (22), 5124-5126.\u00a0 https:\/\/doi.org\/10.1021\/om049340<\/a>+<\/p>\n

Smith, R. C.; Earl, M. J.; Protasiewicz, J. D., \u201cSynthesis and photoluminescent properties of a series of pnictogen-centered chromophores\u201d Inorg. Chem. Acta. <\/em>2004,<\/strong> 357<\/em>, 4139-4143.\u00a0 https:\/\/doi.org\/10.1016\/j.ica.2004.06.051<\/a><\/p>\n

Chen, X.; Smith, R. C.; Protasiewicz, J. D., \u201cCycloaddition of phosphanylidene-s4-phosphoranes ArP:PMe3 and quinones to yield 1,3,2-dioxophospholanes\u201d Chem. Commun. <\/em>2004,<\/strong>\u00a0 (2), 146-147.\u00a0 https:\/\/doi.org\/10.1039\/B309165A<\/a><\/p>\n

Smith, R. C.; Protasiewicz, J. D., \u201cSynthesis and luminescence properties of a series of tris(4-styrylphenyl)phosphorus-(III) and -(V) compounds and of a [Cu(PR3)4]BF4 complex\u201d Dalton Trans. <\/em>2003,<\/strong>\u00a0 (24), 4738-4741.\u00a0 https:\/\/doi.org\/10.1039\/B309735H<\/a><\/p>\n

Smith, R. C.; Chen, X.; Protasiewicz, J. D., \u201cA Fluorescent (E)-Poly(p<\/em>-phenylenephosphaalkene) Prepared by a Phospha-Wittig Reaction\u201d Inorg. Chem. <\/em>2003,<\/strong> 42<\/em>, 5468-5470.\u00a0 https:\/\/doi.org\/10.1021\/ic0345471<\/a><\/p>\n

Smith, R., C.; Shah, S.; Urnezius, E.; Protasiewicz John, D., \u201cAn unusual equilibrium chlorine atom transfer process and its potential for assessment of steric pressure by bulky aryls\u201d J. Am. Chem. Soc. <\/em>2003,<\/strong> 125<\/em> (1), 40-41.\u00a0 https:\/\/doi.org\/10.1021\/ja028422r<\/a><\/p>\n

Shah, S.; Eichler, B. E.; Smith, R. C.; Power, P. P.; Protasiewicz, J. D., \u201cSynthesis and Solid State Structures of Increasingly Sterically Crowded 1,4-Diiodo-2,3,5,6-tetraarylbenzenes: A New Series of Bulky Benzenes and Aryls\u201dNew J. Chem. <\/em>2003,<\/strong> 27<\/em>, 442-445.\u00a0 https:\/\/doi.org\/10.1039\/B210577B<\/a><\/p>\n

Scardovi, N.; Garner Philip, P.; Protasiewicz John, D., \u201cS-(2-pyridinyl)-1,1,3,3-tetramethylthiouronium hexafluorophosphate. A new reagent for the synthesis of 2-pyridinethiol esters\u201d Org. Lett. <\/em>2003,<\/strong> 5<\/em> (10), 1633-1635.\u00a0 https:\/\/doi.org\/10.1021\/ol034253j<\/a><\/p>\n

Meprathu, B. V.; Protasiewicz, J. D., \u201cSynthesis and characterization of novel polyvalent organoiodine compounds\u201d ARKIVOC (65th<\/sup> birthday of Professor Anastasios Varvoglis issue) <\/em>2003<\/strong>, 83-90.\u00a0 https:\/\/doi.org\/10.3998\/ark.5550190.0004.610<\/a><\/p>\n

Ling, K.-Q.; Lee, Y.; Macikenas, D.; Protasiewicz, J. D.; Sayre, L. M., \u201cCopper(II)-Mediated Autoxidation of tert-Butylresorcinols\u201d Journal of Organic Chemistry <\/em>2003,<\/strong> 68<\/em> (4), 1358-1366.\u00a0 https:\/\/doi.org\/10.1021\/jo020582y<\/a><\/p>\n

Dutan, C.; Shah, S.; Smith, R. C.; Choua, S.; Berclaz, T.; Geoffroy, M.; Protasiewicz, J. D., \u201cSterically Encumbered Diphosphaalkenes and a Bis(diphosphene) as Potential Multiredox-Active Molecular Switches: EPR and DFT Investigations\u201d Inorg. Chem. <\/em>2003,<\/strong> 42<\/em> (20), 6241-6251.\u00a0 https:\/\/doi.org\/10.1021\/ic030079j<\/a><\/p>\n

Copeland, T.; Shea, M. P.; Milliken, M. C.; Smith, R. C.; Protasiewicz, J. D.; Simpson, M. C., \u201cRaman Excitation Profile of a Sterically Protected Diphosphene [ArP=PAr]\u201d Analytica Chimica Acta <\/em>2003,<\/strong> 496(1-2)<\/em>, 155-163.\u00a0 https:\/\/doi.org\/10.1016\/S0003-2670(03)00996-6<\/a><\/p>\n

Smith, R. C.; Urnezius, E.; Lam, K.-C.; Rheingold, A. L.; Protasiewicz, J. D., \u201cSyntheses and Structural Characterizations of the Unsymmetrical Diphosphene DmpP:PMes* (Dmp = 2,6-Mes2C6H3, Mes* = 2,4,6-tBu3C6H2) and the Cyclotetraphosphine [DmpPPPh]2\u201d Inorg. Chem. <\/em>2002,<\/strong> 41<\/em> (20), 5296-5299.\u00a0 https:\/\/doi.org\/10.1021\/ic025759l<\/a><\/p>\n

Smith, R. C.; Shah, S.; Protasiewicz, J. D., \u201cA role for free phosphinidenes in the reaction of magnesium and sterically encumbered ArPCl2<\/sub> in solution at room temperature\u201d J. Organomet. Chem. <\/em>2002,<\/strong> 646<\/em>, 255-261.\u00a0 https:\/\/doi.org\/10.1016\/S0022-328X(01)01384-5<\/a><\/p>\n

Smith, R. C.; Ren, T.; Protasiewicz, J. D., \u201cA robust, reactive, and remarkably simple to prepare sterically encumbered meta<\/em>-terphenyl ligand\u201d Europ. J. Inorg. Chem. <\/em>2002<\/strong>, 2779-2783.\u00a0 https:\/\/doi.org\/10.1002\/1099-0682(200211)2002:11%3C2779::AID-EJIC2779%3E3.0.CO;2-Q<\/a><\/p>\n

Ling, K.-Q.; Ren, T.; Protasiewicz, J. D.; Sayre, L. M., \u201cStructural correction of the 3-methylindole oxidatively-coupled dimer\u201d Tet. Lett. <\/em>2002,<\/strong> 43<\/em>, 6903-6905.\u00a0 https:\/\/doi.org\/10.1016\/S0040-4039(02)01623-4<\/a><\/p>\n

Urnezius, E.; Lam, K.-C.; Rheingold, A. L.; Protasiewicz, J. D., \u201cTriphosphane formation from the terminal zirconium phosphinidene complex [Cp2Zr:PDmp(PMe3)] (Dmp = 2,6-Mes2C6H3) and crystal structure of DmpP(PPh2)2\u201d J. Organomet. Chem. <\/em>2001,<\/strong> 630<\/em> (2), 193-197.\u00a0 https:\/\/doi.org\/10.1016\/S0022-328X(01)00863-4<\/a><\/p>\n

Shah, S.; Simpson, M. C.; Smith, R. C.; Protasiewicz, J. D., \u201cThree Different Fates for Phosphinidenes Generated by Photocleavage of Phospha-Wittig Reagents ArP:PMe3\u201d J. Am. Chem. Soc. <\/em>2001,<\/strong> 123<\/em> (28), 6925-6926.\u00a0 https:\/\/doi.org\/10.1021\/ja015767l<\/a><\/p>\n

Garner, P.; Dogan, O.; Youngs, W. J.; Kennedy, V. O.; Protasiewicz, J.; Zaniewski, R., \u201cStereocontrolled 1,3-dipolar cycloadditions using Oppolzer\u2019s camphor sultam as the chiral auxiliary for carbonyl stabilized azomethine ylides\u201d Tetrahedron <\/em>2001,<\/strong> 57<\/em> (1), 71-85.\u00a0 https:\/\/doi.org\/10.1016\/S0040-4020(00)00998-4<\/a><\/p>\n

Urnezius, E.; Klippenstein, S. J.; Protasiewicz, J. D., \u201cSterically promoted zirconium-phosphorus pi-bonding: structural investigations of [Cp2Zr(Cl){P(H)Dmp}] and [Cp2Zr{P(H)Dmp}2] (Dmp=2,6-Mes2C6H3)\u201d Inorg. Chim. Acta <\/em>2000,<\/strong>297<\/em> (1-2), 181-190.\u00a0 https:\/\/doi.org\/10.1016\/S0020-1693(99)00335-7<\/a><\/p>\n

Shah, S.; Yap, G. P. A.; Protasiewicz, J. D., \u201cCrystal structure of the phosphanylidene-s4-phosphorane DmpP:PMe3 (Dmp = 2,6-Mes2C6H3) and reactions with electrophiles\u201d J. Organomet. Chem. <\/em>2000,<\/strong> 608<\/em> (1-2), 12-20.\u00a0 https:\/\/doi.org\/10.1016\/S0022-328X(00)00284-9<\/a><\/p>\n

Shah, S.; Protasiewicz, J. D., \u201c\u201dPhospha-variations\u201d On The Themes Of Staudinger and Wittig:\u00a0 Phosphorus analogs of Wittig Reagents\u201d Coordination Chemistry Reviews <\/em>2000,<\/strong> 210\/1<\/em>, 181-201.\u00a0 https:\/\/doi.org\/10.1016\/S0010-8545(00)00311-8<\/a><\/p>\n

Shah, S.; Concolino, T.; Rheingold, A. L.; Protasiewicz, J. D., \u201cSterically Encumbered Systems for Two Low-Coordinate Phosphorus Centers\u201d Inorg. Chem. <\/em>2000,<\/strong> 39<\/em>, 3860-3867.\u00a0 https:\/\/doi.org\/10.1021\/ic0001558<\/a><\/p>\n

Mandal, S.; Macikenas, D.; Protasiewicz, J. D.; Sayre, L. M., \u201cNovel tert-Butyl Migration in Copper-Mediated Phenol Ortho-Oxygenation Implicates a Mechanism Involving Conversion of a 6-Hydroperoxy-2,4-cyclohexadienone Directly to an o-Quinone\u201d J. Org. Chem. <\/em>2000,<\/strong> 65<\/em> (16), 4804-4809.\u00a0 https:\/\/doi.org\/10.1021\/jo991625m<\/a><\/p>\n

Macikenas, D.; Skrzypczak-Jankun, E.; Protasiewicz, J. D., \u201cRedirecting secondary bonds to control molecular and crystal properties of an iodosyl and an iodylbenzene\u201d Angewandte Chemie, International Edition <\/em>2000,<\/strong> 39<\/em> (11), 2007-2010.\u00a0 https:\/\/doi.org\/10.1002\/1521-3773(20000602)39:11%3C2007::AID-ANIE2007%3E3.0.CO;2-Z<\/a><\/p>\n

Urnezius, E.; Shah, S.; Protasiewicz, J. D., \u201cDiphosphene and Phosphoranylidenephosphine Formation from a Terminal Phosphinidene Complex\u201d Phosphorus Sulfur Silicon Relat. Elem. <\/em>1999<\/strong>, 137-139.\u00a0 https:\/\/doi.org\/10.1080\/10426509908546201<\/a><\/p>\n

Shah, S.; Protasiewicz, J. D., \u201cPhosphoranylidenephosphines (R3<\/sub>P=PR) as Phospha-Wittig Reagents\u201d Phosphorus Sulfur Silicon Relat. Elem. <\/em>1999<\/strong>, 343.\u00a0 https:\/\/doi.org\/10.1080\/10426509908053651<\/a><\/p>\n

Meprathu, B. V.; Diltz, S.; Walsh, P. J.; Protasiewicz, J. D., \u201cHypervalent Iodine Nitrene Precursors Bearing N<\/em>-Heterocyclic Rings\u201d Tetrahedron Letters <\/em>1999,<\/strong> 40<\/em>, 5459-5460.\u00a0 https:\/\/doi.org\/10.1016\/S0040-4039(99)01065-5<\/a><\/p>\n

Macikenas, D.; Skrzypczak-Jankun, E.; Protasiewicz, J. D., \u201cA New Class of Iodonium Ylides Engineered as Soluble Primary Oxo and Nitrene Sources\u201d J. Am. Chem. Soc. <\/em>1999<\/strong>, 7164-7165.\u00a0 https:\/\/doi.org\/10.1021\/ja991094j<\/a><\/p>\n

Shah, S.; Protasiewicz, J. D., \u201c\u2019Phospha-Wittig\u2019 reactions using isolable phosphoranylidenephosphines ArP:PR3 (Ar = 2,6-Mes2C6H3 or 2,4,6-But3C6H2)\u201d Chem. Commun. <\/em>1998,<\/strong>\u00a0 (15), 1585-1586.\u00a0 https:\/\/doi.org\/10.1039\/A802722F<\/a><\/p>\n

Ren, T.; Lin, C.; Amalberti, P.; Macikenas, D.; Protasiewicz, J. D.; Baum, J. C.; Gibson, T. L., \u201cBis(micro -N,N\u2019-h2-N,O-h2-N\u2019,O\u2019-di(o-methoxyphenyl)-formamidinato)disilver(I): an interesting coordination geometry for silver(I) and room temperature fluorescence\u201d Inorg. Chem. Comm. <\/em>1998,<\/strong> 1<\/em> (1), 23-26.\u00a0 https:\/\/doi.org\/10.1016\/S1387-7003(98)00007-0<\/a><\/p>\n

Macikenas, D.; Meprathu, B. V.; Protasiewicz, J. D., \u201cSolubilization of the Primary Nitrene Sources (Tosyliminoiodo)arenes (ArINTs)\u201d Tetrahedron Letters <\/em>1998,<\/strong> 39<\/em>, 191-194.\u00a0 https:\/\/doi.org\/10.1016\/S0040-4039(97)10522-6<\/a><\/p>\n

Shah, S.; Burdette, S. C.; Swavey, S.; Urbach, F. L.; Protasiewicz, J. D., \u201cAlkali Metal Induced Rupture of a Phosphorus-Phosphorus Double Bond. Electrochemical and EPR Investigations of New Sterically Protected Diphosphenes and Radical Anions [ArPPAr].bul\u201d Organometallics <\/em>1997,<\/strong> 16<\/em> (15), 3395-3400.\u00a0 https:\/\/doi.org\/10.1021\/om970025f<\/a><\/p>\n

Gopal, D.; Macikenas, D.; Sayre, L. M.; Protasiewicz, J. D., \u201cStructural Determination of a Dimeric Side-Product Accompanying Dihydropyrazine Preparation\u201d Acta. Chem. Scand. <\/em>1997,<\/strong> 51<\/em>, 938-941.\u00a0 https:\/\/doi.org\/10.3891\/acta.chem.scand.51-0938<\/a><\/p>\n

Garner, P.; Cox, P. B.; Anderson, J. T.; Protasiewicz, J.; Zaniewski, R., \u201cUse of Silicon-Based Tethers to Control Diastereofacial Selectivity in Azomethine Ylide Cycloadditions\u201d J. Org. Chem. <\/em>1997,<\/strong> 62<\/em>, 493-498.\u00a0 https:\/\/doi.org\/10.1021\/jo9609034<\/a><\/p>\n

Boucher, M.; Macikenas, D.; Ren, T.; Protasiewicz, J. D., \u201cSecondary Bonding as a Force-Dictating Structure and Solid-State Aggregation of the Primary Nitrene Sources (Arylsulfonylimino)iodoarenes (ArINSO2Ar\u2019)\u201d J. Am. Chem. Soc. <\/em>1997,<\/strong> 119<\/em> (40), 9366-9376.\u00a0 https:\/\/doi.org\/10.1021\/ja971048o<\/a><\/p>\n

Urnezius, E.; Protasiewicz, J. D., \u201cSynthesis and Structural Characterization of New Hindered Aryl Phosphorus Centers (Aryl = 2,6-Dimesitylphenyl)\u201d Main Group Chemistry <\/em>1996,<\/strong> 1<\/em>, 369-372.\u00a0https:\/\/doi.org\/10.1080\/13583149612331338697<\/a><\/p>\n

Protasiewicz, J. D., \u201c(Tosyliminoiodo)benzene at 298 K\u201d Acta. Cryst. C <\/em>1996<\/strong>, 1570-1572.\u00a0 https:\/\/doi.org\/10.1107\/S0108270195016659<\/a><\/p>\n

Lin, C.; Protasiewicz, J. D.; Smith, E. T.; Ren, T., \u201cLinear Free Energy Relationships in Dinuclear Compounds. 2. Inductive Redox Tuning via Remote Substituents in Quadruply Bonded Dimolybdenum Compounds.\u201d Inorg. Chem. <\/em>1996,<\/strong> 35<\/em>, 6422-6428.\u00a0 https:\/\/doi.org\/10.1021\/ic960555o<\/a><\/p>\n

Lin, C.; Protasiewicz, J. D.; Ren, T., \u201cElectronic Tuning Using Remote Substituents in Tetrakis(micro -N,N\u2019-diarylformamidinato)dinickel. Linear Free Energy Relationships in Dinuclear Compounds\u201d Inorg. Chem. <\/em>1996,<\/strong> 35<\/em> (25), 7455-7458.\u00a0 https:\/\/doi.org\/10.1021\/ic960842s<\/a><\/p>\n

Cicero, R. L.; Zhao, D.; Protasiewicz, J. D., \u201cPolymorphism of ((Tosylimino)iodo)-o-toluene: Two New Modes of Polymeric Association for ArINTs\u201d Inorg. Chem. <\/em>1996,<\/strong> 35<\/em> (2), 275-276.\u00a0 https:\/\/doi.org\/10.1021\/ic951031b<\/a><\/p>\n

Protasiewicz, J. D., \u201cReduction of Intermolecular Association in the Sterically Encumbered (Dichloroiodo)Arene ArICl2 (Ar=2,6-bis(3,5- Dichloro-2,4,6-Trimethylphenyl)Benzene)\u201d J. Chem. Soc. Chem. Commun. <\/em>1995,<\/strong> 1116<\/em>, 1115-1116.\u00a0 https:\/\/doi.org\/10.1039\/C39950001115<\/a><\/p>\n

Odom, A. L.; Cummins, C. C.; Protasiewicz, J. D., \u201cNitric Oxide Cleavage: Synthesis of Terminal Chromium(VI) Nitrido Complexes via Nitrosyl Deoxygenation\u201d J. Am. Chem. Soc. <\/em>1995,<\/strong> 117<\/em> (24), 6613-6614.\u00a0 https:\/\/doi.org\/10.1021\/ja00129a034<\/a><\/p>\n

Lin, C.; Protasiewicz, J. D.; Smith, E. T.; Ren, T., \u201cRedox tuning of the dimolybdenum compounds at the ligand periphery: a direct correlation with the Hammett constant of the substituents\u201d Journal of the Chemical Society, Chemical Communications <\/em>1995,<\/strong>\u00a0 (22), 2257-2258.\u00a0 https:\/\/doi.org\/10.1039\/C39950002257<\/a><\/p>\n

Laplaza, C. E.; Odom, A. L.; Davis, W. M.; Cummins, C. C.; Protasiewicz, J. D., \u201cCleavage of the Nitrous Oxide NN Bond by a Tris(amido)molybdenum(III) Complex\u201d J. Am. Chem. Soc. <\/em>1995,<\/strong> 117<\/em> (17), 4999-5000.\u00a0 https:\/\/doi.org\/10.1021\/ja00122a033<\/a><\/p>\n

Cicero, R. L.; Protasiewicz, J. D., \u201cIs pi-Back-Bonding Important for s-Bound Aldehyde and Ketone Complexes? Synthesis and Structural Characterization of Aromatic Aldehyde Complexes of the [CpFe(CO)2]+ Cation\u201d Organometallics <\/em>1995,<\/strong> 14<\/em> (10), 4792-4798.\u00a0 https:\/\/doi.org\/10.1021\/om00010a047<\/a><\/p>\n

Bronk, B. S.; Protasiewicz, J. D.; Pence, L. E.; Lippard, S. J., \u201cReactions of Low-Valent Group V Dicarbonyl Phosphine Complexes with Carbon-Based Electrophiles To Produce Metal Alkyl, Acyl, Carbyne, and Acetylene Complexes\u201d Organometallics <\/em>1995,<\/strong> 14<\/em> (5), 2177-2187.\u00a0 https:\/\/doi.org\/10.1021\/om00005a018<\/a><\/p>\n

Bronk, B. S.; Protasiewicz, J. D.; Lippard, S. J., \u201cReductive Coupling of Group 5 Dicarbonyls to Disiloxyacetylene Complexes: Ring Formation and Effects of Increasing Steric Demands\u201d Organometallics <\/em>1995,<\/strong> 14<\/em> (3), 1385-1392.\u00a0 https:\/\/doi.org\/10.1021\/om00003a044<\/a><\/p>\n

Protasiewicz, J. D.; Bronk, B. S.; Masschelein, A.; Lippard, S. J., \u201cElectrophile-Promoted Carbyne-CO Coupling at a Tantalum Center\u201d Organometallics <\/em>1994,<\/strong> 13<\/em> (4), 1300-1311.\u00a0 https:\/\/doi.org\/10.1021\/om00016a037<\/a><\/p>\n

Mendenhall, G. D.; Protasiewicz, J. D.; Brown, C. E.; Ingold, K. U.; Lusztyk, J., \u201c5-Endo Closure of the 2-Formylbenzoyl Radical\u201d J. Am. Chem. Soc. <\/em>1994,<\/strong> 116<\/em> (5), 1718-1724.\u00a0 https:\/\/doi.org\/10.1021\/ja00084a012<\/a><\/p>\n

Protasiewicz, J. D.; Theopold, K. H., \u201cA direct comparison of the rates of degenerate transfer of electrons, protons, and hydrogen atoms between metal complexes\u201d J. Am. Chem. Soc. <\/em>1993,<\/strong> 115<\/em> (13), 5559-5569.\u00a0 https:\/\/doi.org\/10.1021\/ja00066a025<\/a><\/p>\n

Protasiewicz, J. D.; Masschelein, A.; Lippard, S. J., \u201cKinetic, spectroscopic, and structural evidence for carbene-carbyne intermediates in carbyne\/CO coupling\u201d J. Am. Chem. Soc. <\/em>1993,<\/strong> 115<\/em> (2), 808-810.\u00a0 https:\/\/doi.org\/10.1021\/ja00055a074<\/a><\/p>\n

Carnahan, E. M.; Protasiewicz, J. D.; Lippard, S. J., \u201c15 Years of Reductive Coupling – What Have We Learned?\u201d Accounts of Chemical Research <\/em>1993,<\/strong> 26<\/em> (3), 90-97.\u00a0 https:\/\/doi.org\/10.1021\/ar00027a003<\/a><\/p>\n

Protasiewicz, J. D.; Bianconi, P. A.; Williams, I. D.; Liu, S.; Rao, C. P.; Lippard, S. J., \u201cSynthesis and structural characterization of low-valent Group V phosphine complexes\u201d Inorg. Chem. <\/em>1992,<\/strong> 31<\/em> (20), 4134-4142.\u00a0 https:\/\/doi.org\/10.1021\/ic00046a027<\/a><\/p>\n

Protasiewicz, J. D.; Lippard, S. J., \u201cVanadium-promoted reductive coupling of carbon monoxide and facile hydrogenation to form cis-disiloxyethylenes\u201d J. Am. Chem. Soc. <\/em>1991,<\/strong> 113<\/em> (17), 6564-6570.\u00a0 https:\/\/doi.org\/10.1021\/ja00017a030<\/a><\/p>\n

Protasiewicz, J. D.; Schulte, G.; Theopold, K. H., \u201cElectron transfer rates of a cobalt(1-)\/cobalt(0) couple and crystal structure of the tetrakis(trimethylphosphite)cobaltate(1-) ion\u201d Inorg. Chem. <\/em>1988,<\/strong> 27<\/em> (7), 1133-1136.\u00a0 https:\/\/doi.org\/10.1021\/ic00280a007<\/a><\/p>\n

Protasiewicz, J.; Mendenhall, G. D., \u201cDi-tert-butyl hyponitrite as a source of alkoxyl radicals for dimerization\u201d J. Org. Chem. <\/em>1985,<\/strong> 50<\/em> (17), 3220-3222.\u00a0 https:\/\/doi.org\/10.1021\/jo00217a044<\/a><\/p>\n

 <\/p>\n","protected":false},"excerpt":{"rendered":"

Ekstrom, Zakary T.; Stone, \u00a0Alexander M.; \u00a0Li, Guobi; Hassoun, Hannah D.; \u00a0Kornokovich, Anthony D.; Delgado Rosario, Emalyn; \u00a0Espinosa Ferao, Arturo; \u00a0Zeller, Matthias; Rheingold, Arnold L.; \u00a0Protasiewicz, John D. \u00a0“When Acids and Quinones Replace Metals: Expanding the Toolbox for the Mild Dehydrocoupling of Phosphines<\/em>“, 2026<\/strong>, Inorg. Chem.<\/em> submitted.<\/p>\n

Kornokovich,Anthony D.; Rheingold, Arnold L.; Rikka, Vallabha R.; Tang, Wan Si; Jeevarajan, Judith A.; Protasiewicz, J. D. “Dealkylation as a Strategy to Unconventional Lithium Salts from ortho-Phenyl-phosphonate-boranes<\/em>“, Inorg. Chem.<\/em> 2026<\/strong>, 65<\/em>,<\/p>\n

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